화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2011년 가을 (10/06 ~ 10/07, 김대중 컨벤션센터)
권호 36권 2호
발표분야 의료용 고분자 부문위원회
제목 Study on Microstructure and Phase Transition ofPLA-PEG-PLA Tri-block Copolymer By SAXS & SANS
초록 In recent years many efforts have been made in synthesis of PLA-PEG di- and tri-block copolymers. PLA-PEG block copolymers will self-assemble spontaneously in water into a spherical micelle of a few hundred molecules which has a core of densely packed hydrophobic PLA block and a dense PEG brush shell which radiates from the core. And they occur sol-gel transition by various concentrations and temperature. In this work, PLA-PEG-PLA tri-block copolymers with various block lengths were synthesized. The aqueous solutions of the synthesized block copolymers with different concentrations were prepared and their sol-gel transitions with the detailed microstructures accompanying the transition were examined by the small angle X-ray and neutron scattering (SAXS and SANS).
저자 태선규, 최광복, 전혜진, 송현훈
소속 한남대
키워드 sol-gel transition; PEG; PLA
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