화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2015년 가을 (10/06 ~ 10/08, 대구컨벤션센터(EXCO))
권호 40권 2호
발표분야 분자전자 부문위원회 II
제목 Positively-charged Reduced Graphene Oxide as an Adhesion Promoter for Highly-stable Silver Nanowire Film
초록 In this manuscript, we demonstrated, for the first time, the atomically-thin conductive adhesion promoter of positively-charged reduced graphene oxide (rGO-NH3+) for transparent highly-stable AgNWs TCEs. The insertion of the rGO-NH3+ between AgNWs and polymeric substrate dramatically enhanced both chemical and mechanical stabilities of AgNWs. The AgNWs TCEs assisted with the adhesion promoter were extremely stable under harsh conditions including ultrasonication in various solvents, mechanical bending. This strong adhesion enhancement was originated from the charge transfer from the negatively-charged hydroxo- and oxo-groups onto AgNWs to the positively-charged protonated amine groups in rGO-NH3+, indicating the formation of ionic bonding. Notably, conductive rGO contributed a uniform current distribution of the mesh-type AgNWs. In addition, the 2D layered structure of atomically-thin rGO-NH3+ adhesion promoter could enhance the water protection properties of the AgNWs films.
저자 조정호, 박호석, 김유성, 강형석, 이성준, 손기군
소속 성균관대
키워드 TCE; Silver nanowire; flexible display
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