| 학회 |
한국고분자학회 |
| 학술대회 |
2007년 봄 (04/12 ~ 04/13, 제주 ICC) |
| 권호 |
32권 1호 |
| 발표분야 |
고분자 가공/복합재료 |
| 제목 |
Effective Preparation and Characterization of Montmorillonite/Poly(ε-caprolactone)-based Polyurethane Nanocomposites |
| 초록 |
In this study, montmorillonite (MMT)/poly(ε-caprolactone)-based polyurethane cationomer (MMT/PCL-PUC) nanocomposites were prepared and their mechanical properties, thermal stabilities, and biodegradability were investigated. The PCL-PUC have 3 mol% of quaternary ammonium groups in the main chain. The MMT was successfully exfoliated and well dispersed in the PCL-PUC matrix up to 7 wt% of MMT. As the content of MMT increased in the MMT/PCL-PUC nanocomposites, the degree of microphase separation of the PCL-PUC decreased due to the strong interactions between the PCL-PUC chains and the exfoliated MMT layers. Biodegradability of the MMT/PCL-PUC nanocomposites was dramatically increased with increasing content of MMT likely due to the less phase-separated morphologies of the MMT/PCL-PUC. |
| 저자 |
육지호1, 김태곤1, 정은환1, Jie Yang1, 이한섭1, 서승원2
|
| 소속 |
1인하대, 2(주)효성 |
| 키워드 |
poly(ε-caprolactone) (PCL); polyurethane cationomer (PUC); montmorillonite (MMT); nanocomposits; exfoliation; hydrolytic degradation |
| E-Mail |
|
