| 학회 |
한국공업화학회 |
| 학술대회 |
2010년 봄 (05/13 ~ 05/14, BEXCO(부산)) |
| 권호 |
14권 1호 |
| 발표분야 |
촉매 |
| 제목 |
Novel Aluminum Alkyl Complexes as Catalysts for the Ring Opening Polymerization of ε-Caprolactone |
| 초록 |
Poly(ε-caprolactone) polymers are biodegradable, biocompatible, and non-toxic materials. Al complexes with many initiating groups such as alkoxy, alkyl, and amide have been used as catalytic centers in the ring opening polymerization of ε-caprolactone.However, examples of Al complexes containing ligands with more than three binding site are quite rare. Synthesis and characterization of new alkyl aluminum complexes , their controlled polymerizations of ε-caprolactone(CL) will be demonstrated. Their X-ray structures of five aluminum complexes will be also shown. In addition, the linearity of molecular weight versus conversion in the polymerization of CL will be discussed. |
| 저자 |
김소한1, 이준승2, 이진혁1, 문유경1, 고영수3, 김영조1
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| 소속 |
1충북대, 2전남대, 3공주대 |
| 키워드 |
Poly(ε-caprolactone) polymer; alkyl aluminum complex; tetradentate ligand; linearity
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| E-Mail |
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