학회 |
한국화학공학회 |
학술대회 |
2006년 봄 (04/20 ~ 04/21, 대구 인터불고 호텔) |
권호 |
12권 1호, p.1074 |
발표분야 |
촉매 및 반응공학 |
제목 |
Studies on the water gas shift reaction over ceria-supported precious metals |
초록 |
Water Gas Shift (WGS) reaction is one of the key catalytic stages in a fuel processor and hydrogen station. The commercial low temperature shift (LTS) catalyst (Cu-Zn/Al2O3), though highly active at low temperature, was unsuitable for commercialized applications because of the rapid deactivation tendency under severe conditions. Also, the Cu-Zn/Al2O3 catalyst can not be used at temperatures above about 250℃, which further limits their utility. The WGS reaction over ceria based catalysts was investigated to develop an alternate commercial Cu-Zn/Al2O3 catalyst. The catalyst was prepared by an impregnation method, and were characterized by N2 physisorption, CO chemisorption and XRD. It was found that Cu-Mo/CeO2 catalyst showed higher activity and stability than the commercial LTS catalyst for WGS reaction. |
저자 |
류종우, 이윤주, 심재금, 유계상, 이상득, 문동주
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소속 |
한국과학기술(연) |
키워드 |
WGS; Fuel Cell; Ceria; Fuel Processor; Hydrogen Station
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E-Mail |
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원문파일 |
초록 보기 |