화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2010년 가을 (10/07 ~ 10/08, 대구 EXCO)
권호 35권 2호
발표분야 기능성 고분자
제목 Preparation of PEGMA-co-PFPMA polymer brushes via surface-initiated atom transfer radical polymerization (SI-ATRP)
초록 The surface chemistry, physics, and topography of biomaterials are important parameters that influence the properties of materials. Specifically, polymer brushes are the attractive means to control surface properties of biomaterials. In this study, polymer brushes consisting of PEGMA-co-PFPMA were prepared via SI-ATRP technique as 'grafting from' method that could be high density brushes. For preparation of brushes, SI-ATRP was carrid out after immobilization of bromine-containing material that acted as the initiating moiety of ATRP. The monomer components of brushes are poly(ethylene glycol)methacrylate and 4-formylphenyl methacrylate. It has been generally known that the modification of surface with PEG effectively eliminates protein adsorption. Furthermore, another monomer FPMA including aldehyde group can bond with a variety of bio-substances such as protein and DNA. Thus, surfaces coated PEGMA-co-PFPMA will be discussed for various bio-application fields in this presentation.
저자 이정화, 김정안, 김정순, 김주훈
소속 경희대
키워드 polymer brush; SI-ATRP
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