| 학회 | 한국화학공학회 |
| 학술대회 | 2006년 봄 (04/20 ~ 04/21, 대구 인터불고 호텔) |
| 권호 | 12권 1호, p.39 |
| 발표분야 | 고분자 |
| 제목 | Methyl Acrylate Polymerization with New Zirconium(IV) Complex/MAO System |
| 초록 | Since the 2,6-bis(benzimidazolyl) pyridine (BBIPy) was synthesized for potential complexing agents, several researchers reported the complexes which were contained the BBIPy ligand. We firstly synthesize the Zirconium(IV) complex bearing BBIPy ligand ((BBIPy)ZrCl2). The common feature of methyl acrylate (MA) polymerization method is atom transfer radical polymerization (ATRP). However, Cunningham et al. and other researchers reported about MA polymerization by catalyst with methylaluminoxane (MAO). In this study, the new complex, (BBIPy)ZrCl2 is active catalytic system for the polymerization of MA monomer in the presence of MAO. The polymerization of MA is tried for different conditions such as different temperature, catalyst/MAO ratio, etc. The obtained Poly(methyl acrylate) (PMA) is analyzed by NMR and GPC. The effect of different temperature and MAO/Zr ratio on the polymerization activity of (BBIPy)ZrCl2/MAO is reported. |
| 저자 | 조현용1, 홍대식2, Liqiang Cui1, 나래시 타르테1, 공영대3, 우성일1 |
| 소속 | 1한국과학기술원 / 초미세화학공정시스템 연구센터(CUPS), 2LG화학기술원, 3한국화학(연) |
| 키워드 | Methyl acrylate; Zirconium; MAO |
| 원문파일 | 초록 보기 |
