| 학회 | 한국공업화학회 |
| 학술대회 | 2013년 가을 (10/30 ~ 11/01, 대전컨벤션센터) |
| 권호 | 17권 2호 |
| 발표분야 | 포스터-정밀화학 |
| 제목 | Alternative synthetic studies towards biomass-derived furanic platforms |
| 초록 | Current issues of energy and environment prompt us to replace fossil-based resources with renewable ones. 5-Hydroxymethylfurfural (HMF) has been identified as one of the key intermediates towards these challenging goals. Despite the huge potential for versatile application of HMF, sustainable synthetic routes for its mass production are yet to be developed because of several drawbacks such as ineffective conversion, difficult isolation and relative instability. Numerous studies have been devoted to efficient syntheses of more stable HMF derivatives. Herein we report a simple and eco-friendly synthesis of 5-acetoxymethylfurfural (AcHMF) that can be used as an alternative of HMF. Our research is mainly focused on acid-catalyzed cyclization of the selectively protected sugar by enzymatic or chemical procedures. Successful functionalization of AcHMF into several value-added HMF derivatives is also achieved. |
| 저자 | 강은실1, 김백진2, 조진구2, 김영규1 |
| 소속 | 1서울대, 2한국생산기술(연) |
| 키워드 | biomass; furanic platform; HMF |
